Reviewing Kerala Syllabus Plus One Chemistry Previous Year Question Papers and Answers Pdf Model 2019 helps in understanding answer patterns.
Kerala Plus One Chemistry Board Model Paper 2019
Question 1.
The symbol of the element with atomic number 118 is:
а) Uuu
b) Uuo
c) Ubu
d) Buo
Answer:
а) Uuu
Question 2.
The oxidation state of Cl in HClO. is
Answer:
+7
Question 3.
What is the bond order of 02 molecule?
Answer:
2
Question 4.
Blue Baby Syndrome is caused by excess of …………… in drinking water.
Answer:
NO3– (Nitrate)
Question 5.
Sodium hexa meta phosphate is commercially called:
Answer:
Calgon
Question 6.
Identify the Lewis acid among the following:
a) NH3
b) H20
c) BF3
d) Cl–
Answer:
c) BF3
Question 7.
Suggest a suitable method for the separation of a mixture of aniline and chloroform.
Answer:
Steam distillation
Answer any 10 questions from question number 8 to 20. Each carries 2 score. (10 × 2 = 20)
Question 8.
State and explain law of definite proportion.
Answer:
The law of definite proportion: The same compound always contains same elements in a fixed ratio by mass.
eg: Water always contains hydrogen and oxygen present in a ratio by mass as 2 :16 ie. 1 : 8
Question 9.
What are the two important defects of Rutherford’s nuclear model of atom?
Answer:
Defects of Rutherford’s nuclear model of atom are
i) It couldn’t explain the electronic structure of atom.
ii) It couldn’t explain the stability of an atom.
Question 10.
Give the reason for the deviation of real gases from the ideal gas behaviour.
Answer:
Two faulty assumptions in kinetic theory of gases.
a) There is no force of attraction between the gas molecules.
b) Volume of a gas molecule is negligible compared to the volume of the gas.
Question 11.
Differentiate between extensive and intensive properties with su itable examples.
Answer:
- Extensive properties are those properties which depend upon mass, eg . mass, volume, internal energy, entropy, etc.
- Intensive properties are those properties which are independent of mass, eg: pressure, temperature.
Question 12.
Justify the position of hydrogen in the periodic table.
Answer:
Hydrogen resembles both with alkali metals and halogens. Hydrogen has electronic configuration 1s1 as similar to alkali metals. It loses one electron to form unipositive ions as that of alkali. It can also gain electron to form uninegative ion as that of halogen.
Question 13.
Give the IUPAC name of the following compounds:
Answer:
Question 14.
a) How will you prepare H2O2 in the laboratory?
b) Draw the structure of H2O2 molecule.
Answer:
a) Acidifying barium peroxide with H2S04 and removing excess water by evaporation under reduced pressure gives hydrogen peroxide.
open book like structure or lap top structure.
Question 15.
Suggest a method to convert ethyne to benzene.
Answer:
By passing ethyne through a hot iron tube at 873 K
Question 16.
How will you prepare water gas and producer gas?
Answer:
Water gas is produced by passing steam over red hot coke.
Producer gas (a mixture of (CO & N2) is prepared by passing air over red hot coke.
Question 17.
Account for the following:
a) H2O is a liquid while H2S is a gas at room temperature.
Answer:
Due to the presence of inter molecular hydrogen bonds H2O is a Ijquid. But in H2S there is no hydrogen bond.
(This is because, H2O has intermolecular hydrogen bond between it’s molecule (H-O-H——H-O-H) while H2S has weak Van Der Wals forces between it’s molecule. Hence the molecules of H2O are strongly packed than H2S, thus water is at liquid state at room temperature)
b) BeCl2 molecule has zero dipole moment.
Answer:
In BeCl2 the dipole moments in equal and opposite direction so it cancel each other.
Cl – Be – Cl
Question 18.
When sodium metal dissolves in liquid ammonia it gives a deep blue coloured solution. Explain the reason.
Answer:
The blue colour of the solution is due to the ammoniated electron which absorbs energy in the visible region of light and thus imparts blue colour to the solution.
M + (x + y)NH3 → [M(NH3)x]– +[e(NH3)y]–
Question 19.
Illustrate common ion effect using an example.
Answer:
Common ion effect is the suppression of dissociation of a weak electrolyte by the addition of a strong electrolyte containing a common ion.
eg. Dissociation of NH4Cl is suppressed by adding NH4OH to the solution, (identification of group III in salt analysis)
Question 20.
Illustrate Markovnikov’s rule taking the example of propene.
Answer:
Markonikov’s rule: The negative part of the addentum moves to the a carbon atom which contains less number of hydrogen.
Answer any 7 questions from question number 21 to 29. Each carries 3 score. (7×3 = 21)
Question 21.
Ah organic compound contain the elements C, H and O in the composition C = 54. 24%, H=9.05% and 0=36.71%.If the molecular mass of the compound is 88 u, What is the molecular formula of the compound? (3)
Answer:
Img 8
Empirical formula = C2H4O
Empirical formula mass = 12 × 2 + 4 × 1 + 16
= 24 + 4 + 16
= 44
Molecular mass = 88 MF = (EF) × n
\(\frac{\text { Molecular mass }}{\text { Empirical formula mass }}\) = n = \(\frac{88}{44}\) = 2
Molecular formula = (C2H4O)2 = C4H8O2
Question 22.
a) Write the general outer electronic configuration of d-block elements. (1)
Answer:
ns12 (n-1) d1-10 np1-6
b) The first ionisation enthalpy of sodium is lower than that of magnesium but it’s second ionization enthalpy is higher than that of magnesium. Explain. (2)
Answer:
11Na – 1s2 2s2 2p6 3s1
Removing one electron requires less energy because by removing one electron it will get stable electronic configuration. Hence first IE of Na is lower. Na+ has stable electronic configuration with completed octet as
Na+ – 1 s2 2s2 2p6
Mg – 1s2 2s2 2p6 3s2
In Na+ force of attraction is more and size is less than Mg. So IE2 of Na is more than Mg.
Question 23.
a) Give two similarities between lithium and magnesium (2)
Answer:
1. Both Li and Mg are harder
2. Both Li and Mg combine with N2 to form corresponding nitride Li3N and Mg3N2
3. Li and Mg react slowly with water.
4. LiCl & MgCl2 are deliquescent.
b) When carbon dioxide is passed through lime water, milkiness appears. Give equation for the above reaction. (1)
Answer:
Ca(OH)2 + CO2 → CaCO3 + H2O
Question 24.
Complete the following reactions,
Answer:
Question 25.
a) Define Dalton’s law of partial pressures. (1)
Answer:
The law states that the total pressure of a mixture of non reacting gases is equal to the sum of partial pressures of component gases.
b) Density of a gas was found to be 5.59 K at 27° C and 2 bar pressure. Calculate it’s molecular mass.
(R = 0.083 L atm / mol /K) (2)
Answer:
PV = nRT
Question 26.
Balance the following redox reaction using oxidation number or ion electron method in acidic medium.
Fe2+ + Cr2O2+7 → Fe3+ + Cr3-
a) Explain the bonding in diborane. (2)
b) How will you convert diborane to inorganic benzene? (1)
Answer:
Oxidation number method
1. Skeletal equation is
Fe2+ + Cr2O2+7 → Fe3+ + Cr3-
2. Calculate increase or decrease inn oxidation no.
Question 27.
a) Explain the bonding in diborane.
Answer:
Diborane is an electron deficient compound. In this compound a special type of 3 centered 2 electron bond is formed in addition to 2 centered 2 electron bond. This 3 centered 2 electron bond is also known as bridge bond or banana bond.
In this compound each Boron has 3 electron and each hydrogen atom has one electron ie., a total of 12 electrons. But with these 12 electrons 8 bonds have to be formed. So a Bridge bond is formed between twp boron atom and one hydrogen atoms using 2 electrons.
b) How will you convert diborane to inorganic benzene.
Answer:
3B2H6 + 6NH3 → 3B2H6.2NH3 → 2 B3N3H6 + 12 H2
Question 28.
Calculate the enthalpy of formation of methane from the following data: (3)
Answer: